MORPHOLOGICAL AND MECHANICAL PROPERTIES OF MT. KELUD VOLCANIC ASH REINFORCED POLYESTER AND EPOXY COMPOSITES
DOI:
https://doi.org/10.22441/jtm.v6i2.1189Abstract
The use of suitable waste products as raw materials has become an interesting matter in composite industry nowadays due to the environmental issues. Volcanic ash is one of the waste materials containing a high number of silica. The aim of this study is to examine the morphological and mechanical properties of Mt. Kelud volcanic ash reinforced polyester and epoxy composites. The volcano ash was dried and sieved into 50 mesh then mixed with polyester or epoxy manually for 10 minutes. The ash added into the matrix was varied by 0%, 10%, 20%, 30% and 40% from matrix volume content. For epoxy matrix, the composite with 40 vol. % particles has the highest tensile strength. However, for the polyester/ash composites, the tensile strength continues to decrease with the addition of particles. There is a significant increasing of 47.04 % for polyester and 5.62 % for epoxy in impact strength when 40 vol. % of volcanic ash added into both polymers. The Scanning Electron Microscopy result shows that there is void and agglomeration contained in epoxy/ash composites and crack propagation along the surface of polyester/ash composites that could be the cause of the failure.Downloads
References
Danusso F, Tieghi G. Strength versus composition of rigid matrix particulate composites in Polymer Journal, pages 1385–1390. 1985.
Shao-Yun Fu, Xi-Qiao Feng, Bernd Lauke, Yiu-Wing Mai. Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites in Composites Part B: Engineering, pages 933 – 961. 2008.
Nafar Dastgerdi, G. Marquis, S. Sankaranarayanan, M. Gupta. Fatigue crack growth behavior of amorphous particulate reinforced composites in Composite Strcuctures Journal, pages 782 – 790, 2016.
Dong-Joo Lee. Fracture mechanical model for tensile strength of particle reinforced elastomeric composites in Mechanics of Materials Journal, pages 54 – 60. 2016.
Debnath S, Ranade R, Wunder SL, McCool J, Boberick K, Baran G. Interface effects on mechanical properties of particle-reinforced composites in Dental Materials Journal, pages 677 – 686. 2004.
D.E. Packham. Handbook of adhesion. John Wiley & Sons, Ltd, England, 2005.
R.D. Adams. Adhesive bonding - science, technology and applications. Woodhead Publishing Limited, Cambridge, 2000.
A. Kinloch, J.H. Lee, A.C. Taylor, S. Sprenger, C. Eger, D. Egan. Toughening structural adhesives via nano-and micro-phase inclusions in The Journal of Adhesive, pages 867–873, 2003.
C.B. Bucknall. Toughened plastics. Springer Science+Business Media, London, 1977.
Y. Huang, D.L. Hunston, A.J. Kinloch, C.K. Riew. Mechanisms of toughening thermoset resins in Toughened plastics I: Science and engineering, American Chemical Society, Washington, pages 1–35. 1993.
V.D. Ramos, H.M. Costa, V.L.P. Soares, R.S.V. Nascimento. Modification of epoxy resin: a comparison of different types of elastometer in Polymer Testing Journal, pages 387–394. 2005.
B. Cardwell, A.F. Yee. Toughening of epoxies through thermoplastic crack bridging in Journal of Material Science, pages 5473–5484. 1998.
G.P. Tandon, G.J. Weng A theory of particle-reinforced plasticity in Journal of Applied Mechanics, pages 126–135. 1988.
A.D. Jenkins. Advanced routes for polymer toughening. Polymer Science Library, Elsevier, Amsterdam. 1996.
G. Gkikas, N.M. Barkoula, A.S. Paipetis. Effect of dispersion conditions on the thermo-mechanical and toughness properties of multi walled carbon nanotubes-reinforced epoxy in Composite Part B: Engineering Journal, pages 2697–2705. 2012.
A.Q. Barbosa, L.F.M. da Silva, M.D. Banea, A. Öchsner. Methods to increase the toughness of structural adhesives with micro particles: an overview with focus on cork particles in Materialwissenschaft und Werkstofftechnik Journal, pages 307–325. 2016.
G.J. Withers, Y. Yu, V.N. Khabashesku, L. Cercone, V.G. Hadjiev, J.M. Souza, et al. Improved mechanical properties of an epoxy glass–fiber composite reinforced with surface organomodified nanoclays in Composite Part B: Engineering Journal, pages 175–182. 2015.
Marjetka Conradi. Nanosilica-reinforced polymer composites in Materials and Technology Journal, pages 285 – 293. 2013.
Anderson, T.L., Fracture Mechanics, 2nd Edition, CRC Press, Boca Raton, FL, 1995.
P.A. Tzika, M.C. Boyce, D.M. Parks. Micromechnics of deformation in particle-toughened polyamide in Journal of Mechanical Phys. Solids, pages 1893–1929. 2001.
M. Quaresimin, M. Zappalorto Salviato. A multi-scale and multi mechanism approach for the fracture toughness assessment of polymer nanocomposites in Composites Science and Technology Journal, pages 16 – 21. 2014.
J Cho, M.S. Joshi, C.T. Sun. Effect of inclusion size on mechanical properties of polymeric composites with micro and nano particles in Composites Science and Technology Journal, pages 1941–1952. 2006.
M.F. Serra, M.S. Conconi, G. Suareza, E.F. Agliettia, N.M. Rendtorff. Volcanic ash as flux in clay based triaxial ceramic materials, effect of the firing temperature in phases and mechanical properties in Ceramic International Journal, pages 6169 – 6177. 2015.
Mohammed Seddik Meddah. Durability performance and engineering properties of shale and volcanic ashes concretes in Construction and Building Materials Journal, pages 73 – 82. 2015.
Youngchan Shin, Deokkyu Lee, Kangtaek Lee, Kyung Hyun Ahn, Bumsang Kim. Surface properties of silica nanoparticles modified with polymers for polymer nanocomposite applications in Journal of Industrial and Engineering Chemistry, pages 515 – 519. 2008.
Alisa Boonyapookana, Anchalee Saengsai, Supachai Surapunt, Kohsoku Nagata, Yoshiharu Mutoh. Time dependent fatigue crack growth behavior of silica particle reinforced epoxy resin composite in International Journal of Fatigue, pages 288 – 293. 2016.
Rubens Bagni Torres, Júlio Cesar dos Santos, Túlio Hallak Panzera, André Luis Christoforo, Paulo H. Ribeiro Borges, Fabrizio Scarpa. Hybrid glass fibre reinforced composites containing silica and cement microparticles based on a design of experiment in Polymer Testing Journal, pages 87 – 93. 2016.
Z. Minfeng, S. Xudong, X. Huiquan, J. Genzhong, J. Xuewen, W. Baoyi. Investigation of free volume and the interfacial, and toughening behavior for epoxy resin/rubber composites by positron annihilation in Radiation Physics and Chemistry Journal, pages 245 – 251. 2008.
Y. Huang, A.J. Kinloch. The toughness of epoxy polymers containing microvoids in Polymer Journal, pages 1330 – 1332. 1992.
A.J. Kinloch, D. Hunston. Effect of volume fraction of dispersed rubbery phase on the toughness of rubber-toughened epoxy polymers in Journal of Materials Science, pages 137 – 139. 1987
Downloads
Published
How to Cite
Issue
Section
License
The copyright to this article is transferred to Universitas Mercu Buana (UMB) if and when the article is accepted for publication. The undersigned hereby transfers any and all rights in and to the paper including without limitation all copyrights to UMB. The undersigned hereby represents and warrants that the paper is original and that he/she is the author of the paper, except for material that is clearly identified as to its original source, with permission notices from the copyright owners where required. The undersigned represents that he/she has the power and authority to make and execute this assignment.
We declare that:
1. This paper has not been published in the same form elsewhere.
2. It will not be submitted anywhere else for publication prior to acceptance/rejection by this Journal.
3. A copyright permission is obtained for materials published elsewhere and which require this permission for reproduction.
Furthermore, I/We hereby transfer the unlimited rights of publication of the above mentioned paper in whole to UMB. The copyright transfer covers the exclusive right to reproduce and distribute the article, including reprints, translations, photographic reproductions, microform, electronic form (offline, online) or any other reproductions of similar nature.
The corresponding author signs for and accepts responsibility for releasing this material on behalf of any and all co-authors. This agreement is to be signed by at least one of the authors who have obtained the assent of the co-author(s) where applicable. After submission of this agreement signed by the corresponding author, changes of authorship or in the order of the authors listed will not be accepted.
Retained Rights/Terms and Conditions
1. Authors retain all proprietary rights in any process, procedure, or article of manufacture described in the Work.
2. Authors may reproduce or authorize others to reproduce the Work or derivative works for the authors personal use or for company use, provided that the source and the UMB copyright notice are indicated, the copies are not used in any way that implies UMB endorsement of a product or service of any employer, and the copies themselves are not offered for sale.
3. Although authors are permitted to re-use all or portions of the Work in other works, this does not include granting third-party requests for reprinting, republishing, or other types of re-use.
This work is also licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.









