Investigation on mechanical properties and microstructural characteristic of rice hush ash based geopolymer mortar as patch repair
Abstract
The rapid expansion of the construction sector is increasing cement use, which significantly impacts the environment due to CO2 emissions. Geopolymers are eco-friendly construction materials designed to reduce cement use and potential to be the patching material to rehabilitate the concrete structure. Among these, pozzolanic materials like rice husk ash, rich in aluminosilicate, are abundant and suitable for geopolymer binders. This study explores using rice husk ash and alkali activators (NaOH/Na2SiO3) with different activator percentages (40%, 45%, and 50%) to evaluate their mechanical properties and potential applications as patch repair materials. The research involved formulating an optimal mix design through trial and error in a laboratory setting, followed by curing at 70°C and testing at room temperature. XRF and SEM-EXD analyses were performed to determine the chemical composition and microstructure of the specimens. The activators, NaOH and Na2SiO3, were used in a 1:3.5 ratio with 14M molarity and 2% superplasticizer to enhance workability. Results showed that the geopolymer mortar's highest compressive strength was 8.14 MPa at a 40% activator variation, while the highest split tensile and flexural strengths were 2.50 MPa and 1.00 MPa, respectively, both at a 50% variation. These findings suggest that the mortar is suitable for patch repairs on concrete substrates with compressive strengths below 8 MPa. The mechanical properties of the rice husk ash geopolymer mortar are influenced by the silica, calcium, and alkali activator content, which affect the mortar's strength and density.
Keywords
References
K. L. Scrivener, V. M. John, and E. M. Gartner, “Eco-efficient cements: Potential economically viable solutions for a low-CO2 cement-based materials industry,” Cem Concr Res, vol. 114, pp. 2–26, Dec. 2018, doi: 10.1016/j.cemconres.2018.03.015.
M. Reza Nadi Abiz, M. Reza Esfahani, A. Tanhadoust, M. L. Nehdi, and S. Mohammad Banijamali, “Magnesium nanoparticle modified cement-based composites: Performance and compatibility in repair applications,” Constr Build Mater, vol. 400, p. 132781, Oct. 2023, doi: 10.1016/J.CONBUILDMAT.2023.132781.
E. A. Anisa, R. Afriansya, J. Randisyah, and P. Astuti, “Studi Pemanfaatan Prekursor Fly Ash Lokal pada Self Compacting Geopolymer Concrete (SCGC),” Semesta Teknika, vol. 24, no. 2, pp. 111–119, Nov. 2021, doi: 10.18196/st.v24i2.13075.
P. Astuti, R. Afriansya, E. A. Anisa, and J. Randisyah, “Mechanical properties of self-compacting geopolymer concrete utilizing fly ash,” 2022, p. 020028. doi: 10.1063/5.0094463.
R. Afriansya, E. A. Anisa, P. Astuti, and M. D. Cahyati, “Effect of polypropylene fiber on workability and strength of fly ash-based geopolymer mortar,” E3S Web of Conferences, vol. 429, p. 05006, Sep. 2023, doi: 10.1051/e3sconf/202342905006.
R. Afriansya, P. Astuti, V. S. Ratnadewati, J. Randisyah, T. Y. Ramadhona, and E. A. Anisa, “Investigation of setting time and flowability of geopolymer mortar using local industry and agriculture waste as precursor in Indonesia,” International Journal of GEOMATE, vol. 21, no. 87, 2021, doi: 10.21660/2021.87.j2325.
P. Astuti, R. Afriansya, E. A. Anisa, S. D. Puspitasari, and A. Y. Purnama, “The potential use of agriculture pozzolan waste as supplementary cementitious materials by integrating with biomass,” 2022, p. 040017. doi: 10.1063/5.0104926.
P. Chindaprasirt, C. Jaturapitakkul, W. Chalee, and U. Rattanasak, “Comparative study on the characteristics of fly ash and bottom ash geopolymers,” Waste Management, vol. 29, no. 2, pp. 539–543, Feb. 2009, doi: 10.1016/j.wasman.2008.06.023.
Z. A. Alrowaili, M. M. Alnairi, I. O. Olarinoye, A. Alhamazani, G. S. Alshammari, and M. S. Al-Buriahi, “Radiation attenuation of fly ash and rice husk ash-based geopolymers as cement replacement in concrete for shielding applications,” Radiation Physics and Chemistry, vol. 217, p. 111489, Apr. 2024, doi: 10.1016/J.RADPHYSCHEM.2023.111489.
J. Tashan, “Flexural behavior evaluation of repaired high strength geopolymer concrete,” Compos Struct, vol. 300, p. 116144, Nov. 2022, doi: 10.1016/J.COMPSTRUCT.2022.116144.
Md. Zia ul haq, H. Sood, R. Kumar, P. Chandra Jena, and S. Kumar Joshi, “Eco-friendly approach to construction: Incorporating waste plastic in geopolymer concrete,” Mater Today Proc, Sep. 2023, doi: 10.1016/j.matpr.2023.09.037.
X. Wang, C. Cheng, and D. Wang, “Effect of rice husk ash on mechanical properties of rubber doped geopolymer recycled concrete,” Case Studies in Construction Materials, vol. 20, p. e03406, Jul. 2024, doi: 10.1016/J.CSCM.2024.E03406.
M. Babaee, M. S. H. Khan, and A. Castel, “Passivity of embedded reinforcement in carbonated low-calcium fly ash-based geopolymer concrete,” Cem Concr Compos, vol. 85, pp. 32–43, Jan. 2018, doi: 10.1016/j.cemconcomp.2017.10.001.
Herwani, I. Pane, I. Imran, and B. Budiono, “Compressive Strength of Fly ash-based Geopolymer Concrete with a Variable of Sodium Hydroxide (NaOH) Solution Molarity,” MATEC Web of Conferences, vol. 147, p. 01004, Jan. 2018, doi: 10.1051/matecconf/201814701004.
R. C. Kaze, A. Naghizadeh, L. Tchadjie, Ö. Cengiz, E. Kamseu, and F. U. Chinje, “Formulation of geopolymer binder based on volcanic-scoria and clay brick wastes using rice husk ash-NaOH activator: Fresh and hardened properties,” Sustain Chem Pharm, vol. 40, p. 101627, Aug. 2024, doi: 10.1016/J.SCP.2024.101627.
J. Zou, X. Ma, M. Zhao, Q. Guan, D. Chen, and Y. Chao, “Ternary geopolymer synthesized using self-made rice husk ash-based water glass for removing Cu2+ and Cr3+ from wastewater,” Mater Lett, vol. 367, p. 136556, Jul. 2024, doi: 10.1016/J.MATLET.2024.136556.
S. Feng, C. Ge, Q. Sun, W. Zheng, G. Li, and C. Hu, “Valorization of agriculture waste: Preparation of alkoxysilanes from mixed rice straw and rice husk ash,” Chemical Engineering Journal, vol. 495, p. 153377, Sep. 2024, doi: 10.1016/J.CEJ.2024.153377.
M. K. A. Talib, S. N. H. Arifin, A. Madun, M. F. M. Dan, and F. Pakir, “Effect of Rice Husk Ash (RHA) as a Pozzolan on the Strength Improvement of Cement Stabilized Peat,” Journal of Advanced Research in Applied Mechanics, vol. 114, no. 1, pp. 83–93, 2024.
L. Dembovska, D. Bajare, I. Pundiene, and L. Vitola, “Effect of Pozzolanic Additives on the Strength Development of High Performance Concrete,” Procedia Eng, vol. 172, pp. 202–210, Jan. 2017, doi: 10.1016/J.PROENG.2017.02.050.
K. Bhatrola, N. C. Kothiyal, and S. Kumar Maurya, “Durability & mechanical properties of functionalized multiwalled carbon nanotube incorporated pozzolana portland cement composite,” Mater Today Proc, Jul. 2023, doi: 10.1016/j.matpr.2023.07.178.
E. Lozinguez, J. F. Barthélémy, V. Bouteiller, and T. Desbois, “Contribution of Sacrificial Anode in reinforced concrete patch repair: Results of numerical simulations,” Constr Build Mater, vol. 178, pp. 405–417, Jul. 2018, doi: 10.1016/J.CONBUILDMAT.2018.05.063.
M. S. Ali, E. Leyne, M. Saifuzzaman, and M. S. Mirza, “An experimental study of electrochemical incompatibility between repaired patch concrete and existing old concrete,” Constr Build Mater, vol. 174, pp. 159–172, Jun. 2018, doi: 10.1016/J.CONBUILDMAT.2018.04.059.
P. Astuti, R. S. Rafdinal, H. Hamada, Y. Sagawa, D. Yamamoto, and K. Kamarulzaman, “Effectiveness of Rusted and Non-Rusted Reinforcing Bar Protected by Sacrificial Anode Cathodic Protection in Repaired Patch Concrete,” in IOP Conference Series: Earth and Environmental Science, 2019. doi: 10.1088/1755-1315/366/1/012013.
K. Kawaai, T. Nishida, A. Saito, and T. Hayashi, “Application of bio-based materials to crack and patch repair methods in concrete,” Constr Build Mater, vol. 340, p. 127718, Jul. 2022, doi: 10.1016/J.CONBUILDMAT.2022.127718.
P. Astuti et al., “Engineering Properties of Seawater-Mixed Mortar with Batching Plant Residual Waste as Aggregate Replacement,” SINERGI, vol. 28, no. 2, pp. 381–394, 2024.
Refbacks
- There are currently no refbacks.
SINERGI
Published by:
Fakultas Teknik Universitas Mercu Buana
Jl. Raya Meruya Selatan, Kembangan, Jakarta 11650
Tlp./Fax: +62215871335
p-ISSN: 1410-2331
e-ISSN: 2460-1217
Journal URL: http://publikasi.mercubuana.ac.id/index.php/sinergi
Journal DOI: 10.22441/sinergi

Journal by SINERGI is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License
The Journal is Indexed and Journal List Title by: